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You could try to override the corresponding theme resource for the item selected status.
Like this:
<NavigationView x:Name="NavigationViewControl" >
<NavigationView.Resources>
<SolidColorBrush x:Key="NavigationViewItemBackgroundSelected" Color="Yellow"/>
</NavigationView.Resources>
<NavigationView.MenuItems>
<NavigationViewItem Content="A" x:Name="A" />
<NavigationViewItem Content="B" x:Name="B" />
<NavigationViewItem Content="C" x:Name="C" />
</NavigationView.MenuItems>
</NavigationView>
Thank you.
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